3-chloropropyltriethoxysilane(CAS No: 5089-70-3) supplier
           
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          The anhydrous toluene of 3-chloropropyltriethoxysilane

           

               2015/7/3 14:36:00

          The surface of micelle-templated silicas (MTS) was functionalized by silylation with 3-chloropropyltriethoxysilane in anhydrous toluene.

          The modified sample (Cl–MTS) was then end-capped by vapor phase treatment with hexamethyldisilazane (HMDZ), which led to the AZA–Cl–MTS sample.

          The textural properties of the support were preserved during the different modifications. A comparison of 29Si MAS-NMR spectra of Cl–MTS with those of the parent support (MTS) showed that silylation occurred through nucleophilic attack at silicon atoms located in the hydrophobic part of the surface.

          This mechanism differed from the sol-gel mechanism, which involves H-bonded silanol groups during silylation in polar or aqueous solvent. Residual silanol groups of the Cl-MTS surface were not totally end-capped during HMDZ treatment.

          This result is explained by the steric hindrance of the trimethylsiloxane groups, which would act as umbrellas that protect the surrounding silanol groups.


           


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